Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu

doi:doi:10.11648/j.sjc.20170501.11

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Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe₃O₄@SiO₂ Nanoparticles Coupled with Fluorescence Spectrophotometry

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu

Published in Science Journal of Chemistry (Volume 5, Issue 1)

Received: 18 December 2016 Accepted: 18 January 2017 Published: 6 March 2017

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Abstract

The Ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM]PF₆) was selected from three ILs along with (1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6), 1-hexyl-3-methyl-imidazole hexafluoro-phosphate ([HMIM]PF6), were coated by Fe₃O₄@SiO₂ nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (Fe₃O₄@SiO₂@IL) and establish a new method of magnetic solid phase extraction (MSPE) coupled with Fluorescence spectrophotometry for separation/analysis of Rhodamine B. The results showed that Rhodamine B was adsorbed rapidly byFe₃O₄@SiO₂@[OMIM]PF₆ and eluted by ethanol. Under the optimal conditions the linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.40-140.00 g L^-1, 0.06g L^-1, 0.9993 and 0.45% (n=3, c=10.00 µg L^-1), respectively. The pre-concentration factor of the proposed method was 25-fold. The Fe₃O₄@SiO₂ NPs can be used repeatedly for 10 times. This method has been applied to the determination of Rhodamine B in food samples.

Published in	Science Journal of Chemistry (Volume 5, Issue 1)
DOI	10.11648/j.sjc.20170501.11
Page(s)	1-7
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Rhodamine B, IL-magnetic Nanoparticles, Magnetic SPE, Fluorescence Spectrophotometry

References

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APA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. (2017). Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Science Journal of Chemistry, 5(1), 1-7. https://doi.org/10.11648/j.sjc.20170501.11

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ACS Style

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu. Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Sci. J. Chem. 2017, 5(1), 1-7. doi: 10.11648/j.sjc.20170501.11

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AMA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Sci J Chem. 2017;5(1):1-7. doi: 10.11648/j.sjc.20170501.11

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@article{10.11648/j.sjc.20170501.11,
  author = {Almojtaba Abd Alkhalig Ahmed Bakheet and Xia Shi Zhu},
  title = {Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry},
  journal = {Science Journal of Chemistry},
  volume = {5},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.sjc.20170501.11},
  url = {https://doi.org/10.11648/j.sjc.20170501.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20170501.11},
  abstract = {The Ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM]PF6) was selected from three ILs along with (1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6), 1-hexyl-3-methyl-imidazole hexafluoro-phosphate ([HMIM]PF6), were coated by Fe3O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (Fe3O4@SiO2@IL) and establish a new method of magnetic solid phase extraction (MSPE) coupled with Fluorescence spectrophotometry for separation/analysis of Rhodamine B. The results showed that Rhodamine B was adsorbed rapidly byFe3O4@SiO2@[OMIM]PF6 and eluted by ethanol. Under the optimal conditions the linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.40-140.00 g L-1, 0.06g L-1, 0.9993 and 0.45% (n=3, c=10.00 µg L-1), respectively. The pre-concentration factor of the proposed method was 25-fold. The Fe3O4@SiO2 NPs can be used repeatedly for 10 times. This method has been applied to the determination of Rhodamine B in food samples.},
 year = {2017}
}

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TY  - JOUR
T1  - Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry
AU  - Almojtaba Abd Alkhalig Ahmed Bakheet
AU  - Xia Shi Zhu
Y1  - 2017/03/06
PY  - 2017
N1  - https://doi.org/10.11648/j.sjc.20170501.11
DO  - 10.11648/j.sjc.20170501.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20170501.11
AB  - The Ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM]PF6) was selected from three ILs along with (1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6), 1-hexyl-3-methyl-imidazole hexafluoro-phosphate ([HMIM]PF6), were coated by Fe3O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (Fe3O4@SiO2@IL) and establish a new method of magnetic solid phase extraction (MSPE) coupled with Fluorescence spectrophotometry for separation/analysis of Rhodamine B. The results showed that Rhodamine B was adsorbed rapidly byFe3O4@SiO2@[OMIM]PF6 and eluted by ethanol. Under the optimal conditions the linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.40-140.00 g L-1, 0.06g L-1, 0.9993 and 0.45% (n=3, c=10.00 µg L-1), respectively. The pre-concentration factor of the proposed method was 25-fold. The Fe3O4@SiO2 NPs can be used repeatedly for 10 times. This method has been applied to the determination of Rhodamine B in food samples.
VL  - 5
IS  - 1
ER  -

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Author Information

Almojtaba Abd Alkhalig Ahmed Bakheet

Department of Analytical Chemistry, College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China
Xia Shi Zhu

Department of Analytical Chemistry, College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou, China

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Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. (2017). Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Science Journal of Chemistry, 5(1), 1-7. https://doi.org/10.11648/j.sjc.20170501.11

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ACS Style

Almojtaba Abd Alkhalig Ahmed Bakheet; Xia Shi Zhu. Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Sci. J. Chem. 2017, 5(1), 1-7. doi: 10.11648/j.sjc.20170501.11

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AMA Style

Almojtaba Abd Alkhalig Ahmed Bakheet, Xia Shi Zhu. Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry. Sci J Chem. 2017;5(1):1-7. doi: 10.11648/j.sjc.20170501.11

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@article{10.11648/j.sjc.20170501.11,
  author = {Almojtaba Abd Alkhalig Ahmed Bakheet and Xia Shi Zhu},
  title = {Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry},
  journal = {Science Journal of Chemistry},
  volume = {5},
  number = {1},
  pages = {1-7},
  doi = {10.11648/j.sjc.20170501.11},
  url = {https://doi.org/10.11648/j.sjc.20170501.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20170501.11},
  abstract = {The Ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM]PF6) was selected from three ILs along with (1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6), 1-hexyl-3-methyl-imidazole hexafluoro-phosphate ([HMIM]PF6), were coated by Fe3O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (Fe3O4@SiO2@IL) and establish a new method of magnetic solid phase extraction (MSPE) coupled with Fluorescence spectrophotometry for separation/analysis of Rhodamine B. The results showed that Rhodamine B was adsorbed rapidly byFe3O4@SiO2@[OMIM]PF6 and eluted by ethanol. Under the optimal conditions the linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.40-140.00 g L-1, 0.06g L-1, 0.9993 and 0.45% (n=3, c=10.00 µg L-1), respectively. The pre-concentration factor of the proposed method was 25-fold. The Fe3O4@SiO2 NPs can be used repeatedly for 10 times. This method has been applied to the determination of Rhodamine B in food samples.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Determination of Rhodamine B Pigment in Food Samples by Ionic Liquid Coated Magnetic Core/Shell Fe3O4@SiO2 Nanoparticles Coupled with Fluorescence Spectrophotometry
AU  - Almojtaba Abd Alkhalig Ahmed Bakheet
AU  - Xia Shi Zhu
Y1  - 2017/03/06
PY  - 2017
N1  - https://doi.org/10.11648/j.sjc.20170501.11
DO  - 10.11648/j.sjc.20170501.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 1
EP  - 7
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20170501.11
AB  - The Ionic liquids (IL) 1-octyl-3-methylimidazole hexafluorophosphate ([OMIM]PF6) was selected from three ILs along with (1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6), 1-hexyl-3-methyl-imidazole hexafluoro-phosphate ([HMIM]PF6), were coated by Fe3O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (Fe3O4@SiO2@IL) and establish a new method of magnetic solid phase extraction (MSPE) coupled with Fluorescence spectrophotometry for separation/analysis of Rhodamine B. The results showed that Rhodamine B was adsorbed rapidly byFe3O4@SiO2@[OMIM]PF6 and eluted by ethanol. Under the optimal conditions the linear range, detection limit (DL), correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.40-140.00 g L-1, 0.06g L-1, 0.9993 and 0.45% (n=3, c=10.00 µg L-1), respectively. The pre-concentration factor of the proposed method was 25-fold. The Fe3O4@SiO2 NPs can be used repeatedly for 10 times. This method has been applied to the determination of Rhodamine B in food samples.
VL  - 5
IS  - 1
ER  -

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