Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K

Belcher Fulele; Wilfred A. A. Ddamba

doi:doi:10.11648/j.ajpc.20170602.11

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Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K

Belcher Fulele, Wilfred A. A. Ddamba

Published in American Journal of Physical Chemistry (Volume 6, Issue 2)

Received: 7 February 2017 Accepted: 1 March 2017 Published: 21 March 2017

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Abstract

Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation. values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.

Published in	American Journal of Physical Chemistry (Volume 6, Issue 2)
DOI	10.11648/j.ajpc.20170602.11
Page(s)	6-19
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Difurylmethane, an Amide, Excess Molar Volume, Excess Partial Molar Volume, Binary Mixtures, Dipole-Dipole Interactions, Hydrogen Bond

References

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Belcher Fulele, Wilfred A. A. Ddamba. (2017). Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. American Journal of Physical Chemistry, 6(2), 6-19. https://doi.org/10.11648/j.ajpc.20170602.11

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ACS Style

Belcher Fulele; Wilfred A. A. Ddamba. Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. Am. J. Phys. Chem. 2017, 6(2), 6-19. doi: 10.11648/j.ajpc.20170602.11

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AMA Style

Belcher Fulele, Wilfred A. A. Ddamba. Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. Am J Phys Chem. 2017;6(2):6-19. doi: 10.11648/j.ajpc.20170602.11

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@article{10.11648/j.ajpc.20170602.11,
  author = {Belcher Fulele and Wilfred A. A. Ddamba},
  title = {Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K},
  journal = {American Journal of Physical Chemistry},
  volume = {6},
  number = {2},
  pages = {6-19},
  doi = {10.11648/j.ajpc.20170602.11},
  url = {https://doi.org/10.11648/j.ajpc.20170602.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20170602.11},
  abstract = {Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation.  values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The  values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of  are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The  data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.},
 year = {2017}
}

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TY  - JOUR
T1  - Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K
AU  - Belcher Fulele
AU  - Wilfred A. A. Ddamba
Y1  - 2017/03/21
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpc.20170602.11
DO  - 10.11648/j.ajpc.20170602.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 6
EP  - 19
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20170602.11
AB  - Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation.  values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The  values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of  are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The  data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.
VL  - 6
IS  - 2
ER  -

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Author Information

Belcher Fulele

Department of Chemistry, Faculty of Science, University of Botswana, Gaborone, Botswana
Wilfred A. A. Ddamba

Department of Chemistry, Faculty of Science, University of Botswana, Gaborone, Botswana

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APA Style

Belcher Fulele, Wilfred A. A. Ddamba. (2017). Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. American Journal of Physical Chemistry, 6(2), 6-19. https://doi.org/10.11648/j.ajpc.20170602.11

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ACS Style

Belcher Fulele; Wilfred A. A. Ddamba. Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. Am. J. Phys. Chem. 2017, 6(2), 6-19. doi: 10.11648/j.ajpc.20170602.11

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AMA Style

Belcher Fulele, Wilfred A. A. Ddamba. Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K. Am J Phys Chem. 2017;6(2):6-19. doi: 10.11648/j.ajpc.20170602.11

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@article{10.11648/j.ajpc.20170602.11,
  author = {Belcher Fulele and Wilfred A. A. Ddamba},
  title = {Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K},
  journal = {American Journal of Physical Chemistry},
  volume = {6},
  number = {2},
  pages = {6-19},
  doi = {10.11648/j.ajpc.20170602.11},
  url = {https://doi.org/10.11648/j.ajpc.20170602.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20170602.11},
  abstract = {Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation.  values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The  values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of  are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The  data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.},
 year = {2017}
}

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TY  - JOUR
T1  - Volumetric Properties of (Difurylmethane + an Amide) Binary Mixtures at 293.15K, 298.15K and 303.15 K
AU  - Belcher Fulele
AU  - Wilfred A. A. Ddamba
Y1  - 2017/03/21
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpc.20170602.11
DO  - 10.11648/j.ajpc.20170602.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 6
EP  - 19
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20170602.11
AB  - Densities (ρ) of pure difuryl methane (DFM), N-methylformamide (NMF), N-ethylformamide (NEF), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA) and those of [DFM + (NMF or NEF or DMF or DMA] binary mixtures over the entire composition range, have been measured at (T = 293.15, 298.15 and 303.15) K and atmospheric pressure. Excess molar volumes (), of each binary system were calculated and correlated by the Redlich-Kister equation.  values for each binary system were negative at each of the three temperatures investigated (T = 293.15, 298.15 and 303.15) K. The  values decreased with temperature increase for each of the binary systems investigated. Sign and magnitude of  are discussed in-terms of type and nature of intermolecular interactions that occur in a binary mixture. The  data have been used to derive excess partial molar volumes (), limiting excess partial molar volumes () and limiting partial molar volumes at infinite dilute region () of each component of the binary mixture. Results are discussed in terms of possible intermolecular interactions and structural effects that occur in the binary mixtures.
VL  - 6
IS  - 2
ER  -

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